Product ID:PRESTONE DE-ICER, AS242,AS240
MSDS Date:01/24/1991
FSC:6850
NIIN:00D020141
MSDS Number: CCBQM

FIRST BRANDS CORP

83 WOOSTER HEIGHTS RD, BLDG 301
DANBURY, CT 06813-1911
US

Emergency Phone: 203-731-2300, CHEMTREC 800-424-9300

Info Phone: 203-731-2300, 803-554-4208

Preparer: 0002)

Cage: DO273

PRESTONE PRODUCTS CORP

DANBURY, CT 06810-5109 US

Telephone: 203-731-3686/830-7865

Cage: 0CXZ7

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 5-9%

ACGIH TLV: C STEL39PPM,A4,VAP96

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 70-80%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 96

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPYLENE GLYCOL

CAS: 57-55-6

RTECS: TY2000000

Fraction By Weight: 5-9%

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 1-5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;96

#6.

RTECS: 9999999ZZ

Fraction By Weight: >1%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5-9%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST:NAU,ABD PAIN,VOMIT,SHORTNES SOF
BREATH,FTG,LEG CRAMPS,CNS EFFECTS,BLUR/DOUBLE VISION,COLOR
PERCEPTION CHANGES,LIVE/KIDNEY/HEART MUSCULE INJURY,METABOLIC
ACIDOSIS,BLINDNESS,GI/CNS EEFECTS,CARDIA C FAILURE,PULM EDEMA.SKIN
ABSORPT:PROL/WIEDESPREAD CONTACT RESULT IN HARMFUL AMTS
ABSORPTED.INHAL:DIZZ,DROWS,(SUPPLEM)
Explanation of Carcinogenicity:PER MSDS:NONE OF INGREDIENTS IN PRODUCT
LISTED AS CARCINOGEN(OR SUSPECTED CARCINOGEN) BY OSHA/NTP/IARC.
Effects of Overexposure:CUMULATIVE EFFECT TO OCCUR W/RESULTING
NAU,VOMIT,HEAD,RINGING IN EARS,INSOMNIA,TREMBLING,UNSTEADY
GAIT,VERTIGO,CLOUDED/DOUBLE VISION.LIVER &/OR KIDNEY INJURY.SEVERE
EYE DMG IN SOME PEOPLE.CNS INVOLVEM NT,PARTICULARLY DIZZINESS &
NYSTAGMUS.SKIN SENS W/DEVELOPMENT OF ALLERGIC CONTACT DERM.
Medical Cond Aggravated by Exposure:DUE TO DEFATTING PROPERTIES
METHANOL MAY AGGRAVATE EXISTING SKIN CONDITIONS E.G.ECZEMA.DUE TO
LIVER/KIDNEY INJURING POTENTIAL PORDUCT MAY EXACERBATE EXISTING
LIVER &/OR KIDNEY DISEASES.

First Aid:INGEST:GIVE 2 GLASSES OF WATER.INDUCE VOMIT IMMED.NEVER GIVE
ANYTHING BY MOUTH IF UNCONSC.GET MED AID IMMED.ETHANOL EFFECTIVE
ANTIDOTE.SKIN:REMOVE CONTAMIN CLOTH.IMMED WASH W/SOAP/COP AMTS OF
WATER.IR RIT/RED OCCUR GET MED ATTN.INHAL:FRESH AIR.BREATH DIFFI
GIVE OXY.BREATH STOP GET ART RESP.GET IMMED MED ATTN.EYE:IMMED
FLUSH W/COP AMTS OF WATER MIN 15MINS.SYMPT OCCUR GET MED ATTN.

Flash Point Method:TOC
Flash Point:69.0F,20.6C
Autoignition Temp:Autoignition Temp Text:N/DETE
Lower Limits:N/DETERMINE
Upper Limits:N/DETERMINE
Extinguishing Media:FOAM, ALCOHOL FOAM, CAROBN DIOXIDE, DRY CHEMICAL
FOR SM FIRES.WATERFOG FOR LARGE FIRES.
Fire Fighting Procedures:NONE; HOWEVER FIREFIGHTING USE SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:AEROSOL FLAME EXTENSION:>18INCHES.
FLASHBACK:NONE.DON'T INCINERATE AEROSOL CNTNR/STORE IN AREA
>120F.CANS OF PACKAGED PRODUCT MAY RUPTURE IF EXPOSED TO HEAT.

Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQPMT & REMOVE ALL
SOURCES OF IGNITION.COLLECT FOR DISPOSAL. IN CNTNR SUITABLE FOR
FLAMM WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER:FLAMM.MAY BE FATAL/CAUSE
BLINDNESS IF SWALLOWED.DON'T SWALLOWE/BREATH VAP.USE ONLY
W/ADEQUATE VENTI.AVOID EYE/SKIN/CLOTH CONTACT.
Other Precautions:WASH EXPO SKIN W/SOAP/WATER.KEEP AWAY FROM SOURCES OF
HEAT/SPARKS/FLAME/OUT OF DIRECT SUNLIGHT.DON'T EXPO TO TEMP
>120F.OBSERVE ALL REQMPTS OF PLANT/CO/GOVT REGS.KEEP OUT OF REACH
OF CHILDREN.LEVEL 1 AEROSOL (NFPA 30B).

Respiratory Protection:OPERATIONS WHERE TLV EXCEEDED NIOSH/MSHA
APPROVED SUPPLIED AIR RESP RECOMMENDED.DOR NOT RELIABLE INDICATOR
OF OVEREXPO SO AIR-PURIFYING EQPMT NOT RECOMMENDED.SELECTION
DEPENDS:CONTAMIN TYP,CONC,29CFR1 910.134,GOOD INDUST HYG PRAC.
Ventilation:GEN(MECH)VENTI ADEQUATE FOR NORMAL USE.OPERATIONS TLV
EXCEEDED FORCEC VENTI(LOC EXHAUS)NEEDED TO MAINTAIN EXPO BEL LIMIT
Protective Gloves:NITRILE,BUTYL RUBB (CHEM RESISTANT)GLOVE
Eye Protection:SPLASH-PROOF GOGGLES RECOMMENDED.
Other Protective Equipment:PROT CLOTH IF NEEDED TO AVOID PROL/REP SKIN
CONTACT.SUITABLE WASH/EYE FLUSH FACILIT AVAILABLE IN WORKAREA.
Work Hygienic Practices:CONTAMIN CLOTH SHOULD BE REMOVED & LAUNDERED
BEFORE REUSE.
Supplemental Safety and Health
APPEARANCE:APPEARANCE,MILD ODOR. HEALTH HAZ:VISION
DISTURBANCE,NUMBNESS,SHOOTING PAINS IN HANDS/FOREARMS,NOSE/THROAT
IRRIT,HEAD,NAU,VOMIT,DIZZ,IRREG EYE
MOVEMENTS.SKIN:REDENING,DEFATTING.EYE:DISCOMFOR T W/MILD
RED,SWELLING OF CONJUNCTIVA,TEMP SUPERFICIAL CORNEA INJURY.

HCC:F3
Boiling Pt:B.P. Text:157F,69C
Melt/Freeze Pt:M.P/F.P Text:>-100F,>-73
Decomp Temp:Decomp Text:NP
Vapor Pres:47
Vapor Density:>1
Spec Gravity:DENS:7.14LB/GAL
pH:SUPPLE
Viscosity:NP
Evaporation Rate & Reference:6 (N-BUTYL ACETATE=1)
Solubility in Water:100% COMPLETE.
Appearance and Odor:CLEAR, COLORLESS LIQUID; ALCOHOL ODOR.
Percent Volatiles by Volume:100
Corrosion Rate:NP

Stability Indicator/Materials to Avoid:YES
NORMALLY NONE.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CO OR CO2.

Waste Disposal Methods:WASTE MATL IS RCRA HAZ WASTE DUE TO
IGNITABILITY.INCINERATION/LANDFILLING SHOULD BE CARRIED OUT IAW
APPLICABLE RCRA FED/STATE/LOC REGS.CONTAINS CHEM SUBJ TO SARA TITLE
III SEC 313 REPORTING:METHANOL, ETHYLENE GLYCOL.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
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particular situation.